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Question
which electron configuration represents a violation of hunds rule for an atom in its ground state?
Hund's rule states that electrons in degenerate orbitals (same - energy orbitals like the three 2p orbitals) first fill each orbital singly with parallel spins before pairing up. In the fourth option, in the 2p sub - shell, electrons are paired in one orbital before all the 2p orbitals have one electron each, which violates Hund's rule.
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The electron configuration with 1s $\uparrow\downarrow$, 2s $\uparrow\downarrow$, 2p $\uparrow\downarrow$ $\square$ $\square$ represents a violation of Hund's rule.