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Question
- a compound consists of 72.2% magnesium and 27.8% nitrogen by mass. what is the empirical formula? element mass (g) atomic mass mole mole ratio empirical formula:
Step1: Assume 100g of the compound
Since the percentages are given by mass, assuming 100g of the compound means there are 72.2g of magnesium (Mg) and 27.8g of nitrogen (N).
Step2: Calculate the moles of each element
The molar mass of Mg is approximately 24.31 g/mol, and for N is approximately 14.01 g/mol.
The number of moles of Mg, $n_{Mg}=\frac{72.2g}{24.31g/mol}\approx2.97mol$.
The number of moles of N, $n_{N}=\frac{27.8g}{14.01g/mol}\approx1.98mol$.
Step3: Find the mole - ratio
Divide each number of moles by the smaller number of moles. Here, 1.98mol is smaller.
The mole - ratio of Mg:$ \frac{2.97mol}{1.98mol}\approx1.5$.
The mole - ratio of N: $\frac{1.98mol}{1.98mol} = 1$.
Since we need whole - number ratios, multiply both by 2 to get a ratio of Mg:N = 3:2.
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The empirical formula is $Mg_3N_2$