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it conveys a multiplicity of feelings from happy reverie to wistful misgivings about the future, while the painted face, academically impeccable, is inert. source: new york times in this sentence, impeccable means: without fault or error pleasant - smelling relating to preparing and dispensing drugs and medicines marked by exaggerated feelings of euphoria
The word "impeccable" generally means without any faults or errors. In the context of the sentence, it describes the painted - face as being academically flawless. The other options do not fit the context. "Pleasant - smelling" is about odor, "relating to preparing and dispensing drugs and medicines" is about pharmacy, and "marked by exaggerated feelings of euphoria" is about a state of extreme happiness, none of which make sense when describing something as "academically" something.
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A. without fault or error