QUESTION IMAGE
Question
predict the approximate bond angle in the molecule.
o(=o^+)-o^- (with lone pairs as shown in the image)
bond angle:
Step1: Identify central atom
The central atom is the positively charged oxygen ($\text{O}^+$).
Step2: Count electron domains
The central $\text{O}^+$ has: 1 double bond, 1 single bond, 1 lone pair. Total electron domains = 3.
Step3: Determine electron geometry
3 electron domains correspond to trigonal planar electron geometry, ideal bond angle $120^\circ$.
Step4: Adjust for lone pair
Lone pair-bond pair repulsion is stronger than bond pair-bond pair repulsion, so the bond angle is slightly less than $120^\circ$.
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Approximately $117^\circ$ (or slightly less than $120^\circ$)