QUESTION IMAGE
Question
table 1: standard solution preparation and absorbance data
calculate the concentration of each standard solution. the absorbance values have been provided for you.
| standard 1 | standard 2 | standard 3 | standard 4 | standard 5 | unknown sample data | |
|---|---|---|---|---|---|---|
| distilled h₂o (ml) | 8.0 | 6.0 | 4.0 | 2.0 | 0 | |
| concentration (m) | ||||||
| absorbance | 0.205 | 0.399 | 0.592 | 0.785 | 0.979 | 0.667 |
the absorbance of your unknown cuso₄ solution was measured to be 0.667.
Step1: Calculate total volume for each standard
For each standard, the total volume $V_{total}$ is the sum of the volume of $0.40\ M\ CuSO_4$ and the volume of distilled $H_2O$. For example, for Standard 1: $V_{total1}=2.0 + 8.0=10.0\ mL$.
Step2: Use dilution formula $C_1V_1 = C_2V_2$
The dilution formula is $C_1V_1 = C_2V_2$, where $C_1$ is the initial concentration ($0.40\ M$), $V_1$ is the volume of the initial solution, $V_2$ is the total volume of the diluted solution, and $C_2$ is the concentration of the diluted solution.
For Standard 1:
$C_1 = 0.40\ M$, $V_1=2.0\ mL$, $V_2 = 10.0\ mL$.
$C_2=\frac{C_1V_1}{V_2}=\frac{0.40\ M\times2.0\ mL}{10.0\ mL}=0.08\ M$.
For Standard 2:
$C_1 = 0.40\ M$, $V_1 = 4.0\ mL$, $V_2=4.0 + 6.0=10.0\ mL$.
$C_2=\frac{0.40\ M\times4.0\ mL}{10.0\ mL}=0.16\ M$.
For Standard 3:
$C_1 = 0.40\ M$, $V_1=6.0\ mL$, $V_2=6.0 + 4.0 = 10.0\ mL$.
$C_2=\frac{0.40\ M\times6.0\ mL}{10.0\ mL}=0.24\ M$.
For Standard 4:
$C_1 = 0.40\ M$, $V_1=8.0\ mL$, $V_2=8.0+2.0 = 10.0\ mL$.
$C_2=\frac{0.40\ M\times8.0\ mL}{10.0\ mL}=0.32\ M$.
For Standard 5:
$C_1 = 0.40\ M$, $V_1 = 10.0\ mL$, $V_2=10.0+0=10.0\ mL$.
$C_2=\frac{0.40\ M\times10.0\ mL}{10.0\ mL}=0.40\ M$.
| Standard | Concentration (M) |
|---|---|
| Standard 2 | 0.16 |
| Standard 3 | 0.24 |
| Standard 4 | 0.32 |
| Standard 5 | 0.40 |
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| Standard | Concentration (M) |
|---|---|
| Standard 2 | 0.16 |
| Standard 3 | 0.24 |
| Standard 4 | 0.32 |
| Standard 5 | 0.40 |