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Question
test review: periodicity
3s²3p¹
4s²3d¹⁰4p⁵
periodic trends:
- what is periodicity?
- what is atomic radius?
- how does the atomic radius change going across a period? why?
- how does the atomic radius change going down a group? why?
- for each of the following pairs, circle the larger atom.
a. y or rb
f. k or na
b. li or be
g. be or b
c. b or c
h. n or o
d. mg or sr
i. ba or ra
e. na or mg
j. ne or f
- what is an ion? how is it different from a neutral atom?
- what is the name of a positively charged ion? ____ does it gain or lose electrons? __ are they usually metals or non - metals? ____
- what is the name of a negatively charged ion? ____ does it gain or lose electrons? __ are they usually metals or non - metals? ____
- which is larger, k or k⁺¹? why?
- which is larger, br, or br⁻¹? why?
- ______ (metal or non - metal) ionic radii are larger than its atomic radius
- ______ (metal or non - metal) ionic radii are smaller than its atomic radius.
- for each of the following elements in each pair, decide whose ion (ionic radii) will be smaller
a. na or br
b. ca or f
c. k or c
d. o or mg
Question 1: What is Periodicity?
Periodicity refers to the repeating pattern of chemical and physical properties of elements in the periodic table as their atomic number increases. This occurs because of the periodic nature of electron configurations, where elements with similar electron arrangements (in the same group) show similar properties. For example, alkali metals (Group 1) all have one valence electron and exhibit similar reactivity, like reacting vigorously with water.
Atomic radius is a measure of the size of an atom. It can be defined as the distance from the nucleus of an atom to the outermost shell of electrons. There are different types of atomic radii (covalent radius, metallic radius, van der Waals radius) depending on the bonding state of the atom. For a non - bonded atom, the van der Waals radius is used, while for a bonded atom (e.g., in a molecule), the covalent radius (for non - metals) or metallic radius (for metals) is considered.
Step1: Identify the trend across a period
As we move from left to right across a period (horizontal row) in the periodic table, the atomic radius generally decreases.
Step2: Explain the reason
The number of protons in the nucleus (atomic number) increases as we move across a period. At the same time, electrons are added to the same valence shell. The increased positive charge of the nucleus exerts a stronger pull on the valence electrons, pulling them closer to the nucleus. Since the electrons are added to the same shell, there is no significant increase in electron - electron shielding to counteract this increased nuclear pull. For example, in the second period, from Li to Ne, the atomic number increases from 3 to 10, and the atomic radius decreases.
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Periodicity is the repeating pattern of chemical and physical properties of elements in the periodic table with increasing atomic number, due to periodic electron - configuration trends.