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Question
what is the formal charge of phosphorus in the lewis structure shown here? options: -2, -1, +1, 0 (with corresponding colored boxes)
Step1: Recall formal charge formula
The formula for formal charge (\(FC\)) is \(FC = V - N - \frac{B}{2}\), where \(V\) is the number of valence electrons in the free atom, \(N\) is the number of non - bonding electrons, and \(B\) is the number of bonding electrons.
For phosphorus (\(P\)):
- The number of valence electrons in a free \(P\) atom, \(V = 5\) (since \(P\) is in group 15 of the periodic table).
- From the Lewis structure, we can see the number of non - bonding electrons (\(N\)): Looking at the Lewis structure of the compound (which has \(P\) bonded to \(O\) and \(F\) atoms), the \(P\) atom has no non - bonding electrons, so \(N = 0\).
- The number of bonding electrons (\(B\)): Let's count the bonds. \(P\) is double - bonded to \(O\) (2 bonds, so 4 electrons) and single - bonded to 3 \(F\) atoms (3 bonds, so 6 electrons). So the total number of bonding electrons \(B=4 + 6=10\)? Wait, no, wait. Wait, in the Lewis structure, for the \(P\) atom: the double bond with \(O\) contributes 2 bonds (4 electrons) and the three single bonds with \(F\) contribute 3 bonds (6 electrons). But when calculating formal charge, we consider the number of bonding electron pairs? Wait, no, the formula is \(FC=V - (N + \frac{B}{2})\), where \(B\) is the number of bonding electrons. Wait, actually, the correct formula is \(FC = \text{Valence electrons in free atom}-\text{Non - bonding electrons}-\text{Bonding electrons}/2\).
Wait, let's re - examine the Lewis structure. The Lewis structure shows \(P\) bonded to one \(O\) (double bond) and three \(F\) atoms (single bonds). So:
- Valence electrons of \(P\) (\(V\)): 5.
- Non - bonding electrons on \(P\) (\(N\)): 0 (since all electrons around \(P\) are in bonds).
- Bonding electrons (\(B\)): In a double bond, there are 4 bonding electrons, and in each single bond, there are 2 bonding electrons. So for \(P\), the number of bonding electrons is \(4+3\times2 = 10\)? Wait, no, that can't be. Wait, no, the formula is \(FC=V-(N + \frac{B}{2})\), where \(B\) is the number of bonding electrons. Wait, actually, the correct formula is \(FC=\text{Number of valence electrons in neutral atom}-\text{Number of non - bonding electrons}-\frac{\text{Number of bonding electrons}}{2}\).
Wait, let's take the atoms:
- For \(O\): Valence electrons \(V = 6\). Non - bonding electrons: 4 (the two lone pairs). Bonding electrons: 4 (double bond). So \(FC_O=6 - 4-\frac{4}{2}=6 - 4 - 2 = 0\).
- For \(F\): Valence electrons \(V = 7\). Non - bonding electrons: 6 (three lone pairs). Bonding electrons: 2 (single bond). So \(FC_F=7 - 6-\frac{2}{2}=7 - 6 - 1 = 0\).
Now for \(P\):
Valence electrons \(V = 5\). Non - bonding electrons \(N = 0\) (no lone pairs on \(P\)). Bonding electrons \(B\): The double bond with \(O\) has 4 electrons, and each single bond with \(F\) has 2 electrons. So total bonding electrons \(B = 4+3\times2=10\)? Wait, no, that's wrong. Wait, the number of bonds: \(P\) has a double bond (2 bonds) with \(O\) and three single bonds (3 bonds) with \(F\). So total number of bonds is \(2 + 3=5\), and the number of bonding electrons is \(5\times2 = 10\)? Wait, no, each bond has 2 electrons. So for \(P\), the number of bonding electrons is \(10\)? Then \(FC_P=5-0-\frac{10}{2}=5 - 5=0\)? Wait, that can't be. Wait, maybe I made a mistake. Wait, the formula is \(FC = V - N - \frac{B}{2}\), where \(B\) is the number of bonding electrons. Wait, let's check the overall charge of the ion. The ion is \(POF_3\)? Wait, no, looking at the Lewis structure, the overall charge of the ion: let's calculate the sum of formal charges.…
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