QUESTION IMAGE
Question
how many single bonds are bonded to sulfur in sf₆?
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question 18
1 pts
in the following lewis structure for clo₃f, chlorine has a formal charge of _ and an oxidation number of _.
1,1
7,1
7,7
1,7
Question 1: How many single bonds are bonded to sulfur in SF₆?
Step1: Analyze SF₆ structure
In SF₆, sulfur (S) is the central atom and is bonded to six fluorine (F) atoms. Each S - F bond is a single bond.
Step2: Count single - bonds
There are 6 S - F single bonds.
Step1: Calculate formal charge of Cl
The formula for formal charge is $FC = V - N - \frac{B}{2}$, where $V$ is the number of valence electrons, $N$ is the number of non - bonding electrons, and $B$ is the number of bonding electrons. Chlorine has 7 valence electrons. In $ClO_3F$, chlorine has 0 non - bonding electrons and 8 bonding electrons. So, $FC=7 - 0-\frac{8}{2}=7 - 4 = 3$. But usually in $ClO_3F$ structure considering resonance and correct distribution, the formal charge of Cl is 0. Because Cl has 7 valence electrons, 0 non - bonding electrons and 7 bonding electrons in the most stable resonance form ($FC = 7-0 - \frac{7}{1}=0$).
Step2: Calculate oxidation number of Cl
Oxygen has an oxidation number of - 2 and fluorine has an oxidation number of - 1. Let the oxidation number of Cl be $x$. In $ClO_3F$, we have $x+3\times(- 2)+(-1)=0$. Solving for $x$ gives $x - 6 - 1=0$, so $x = +7$.
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