QUESTION IMAGE
Question
i
organic chemistry:
- draw structural, condensed or line structural diagrams for the following molecules.
3 - ethylhexan - 2 - ol
1,3 - difluorobenzene
propyl butanoate
1. 3 - ethylhexan - 2 - ol
Step 1: Identify the parent chain
The parent chain is hexane, which has 6 carbon atoms. So the carbon skeleton of the parent chain is \( \text{C}-\text{C}-\text{C}-\text{C}-\text{C}-\text{C} \).
Step 2: Identify the functional group and its position
The functional group is a hydroxyl group (\( -\text{OH} \)) at the 2nd carbon atom. So we attach \( -\text{OH} \) to the 2nd carbon: \( \text{C}-\text{C}(\text{OH})-\text{C}-\text{C}-\text{C}-\text{C} \).
Step 3: Identify and attach the substituent
The substituent is an ethyl group (\( -\text{C}_2\text{H}_5 \)) at the 3rd carbon atom. So we attach \( -\text{C}_2\text{H}_5 \) to the 3rd carbon. The condensed structure is \( \text{CH}_3-\text{CH}(\text{OH})-\text{CH}(\text{C}_2\text{H}_5)-\text{CH}_2-\text{CH}_2-\text{CH}_3 \). The line - bond (skeletal) structure:
CH3
|
CH3 - CH - CH - CH2 - CH2 - CH3
| |
OH CH2CH3
2. 1,3 - difluorobenzene
Step 1: Draw the benzene ring
The parent structure is a benzene ring (\( \text{C}_6\text{H}_6 \) with a cyclic, conjugated double - bond system).
Step 2: Attach the fluorine substituents
We attach fluorine atoms (\( -\text{F} \)) at the 1st and 3rd carbon atoms of the benzene ring. The line - bond structure is:
F
|
C - C - C - F
| | |
C C C
| | |
C - C - C
(where the carbons are part of the benzene ring, and the double bonds are distributed in the conjugated system. The condensed formula can be represented as \( \text{C}_6\text{H}_4\text{F}_2 \) with the two F atoms at positions 1 and 3 relative to each other on the benzene ring.)
3. Propyl butanoate
Step 1: Identify the functional group and the two parts of the ester
Propyl butanoate is an ester. Esters have the general formula \( \text{RCOOR}' \), where \( \text{RCOO}^- \) comes from the carboxylic acid (butanoic acid) and \( \text{R}' \) comes from the alcohol (propanol).
Step 2: Derive the structure from the acid and alcohol parts
- The butanoate part: Butanoic acid has the formula \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COOH} \). When it forms the ester, it becomes \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COO}^- \).
- The propyl part: Propanol has the formula \( \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \). When it forms the ester, the \( -\text{OCH}_2\text{CH}_2\text{CH}_3 \) part comes from propanol.
- The condensed structure of propyl butanoate is \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COOCH}_2\text{CH}_2\text{CH}_3 \). The line - bond structure:
CH3 - CH2 - CH2 - C(=O) - O - CH2 - CH2 - CH3
Final Answers (Structures)
- 3 - ethylhexan - 2 - ol: Condensed: \( \text{CH}_3-\text{CH}(\text{OH})-\text{CH}(\text{C}_2\text{H}_5)-\text{CH}_2-\text{CH}_2-\text{CH}_3 \); Skeletal: As shown above.
- 1,3 - difluorobenzene: Skeletal: As shown above; Condensed: \( \text{C}_6\text{H}_4\text{F}_2 \) (with F at 1 and 3).
- Propyl butanoate: Condensed: \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COOCH}_2\text{CH}_2\text{CH}_3 \); Skeletal: As shown above.
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1. 3 - ethylhexan - 2 - ol
Step 1: Identify the parent chain
The parent chain is hexane, which has 6 carbon atoms. So the carbon skeleton of the parent chain is \( \text{C}-\text{C}-\text{C}-\text{C}-\text{C}-\text{C} \).
Step 2: Identify the functional group and its position
The functional group is a hydroxyl group (\( -\text{OH} \)) at the 2nd carbon atom. So we attach \( -\text{OH} \) to the 2nd carbon: \( \text{C}-\text{C}(\text{OH})-\text{C}-\text{C}-\text{C}-\text{C} \).
Step 3: Identify and attach the substituent
The substituent is an ethyl group (\( -\text{C}_2\text{H}_5 \)) at the 3rd carbon atom. So we attach \( -\text{C}_2\text{H}_5 \) to the 3rd carbon. The condensed structure is \( \text{CH}_3-\text{CH}(\text{OH})-\text{CH}(\text{C}_2\text{H}_5)-\text{CH}_2-\text{CH}_2-\text{CH}_3 \). The line - bond (skeletal) structure:
CH3
|
CH3 - CH - CH - CH2 - CH2 - CH3
| |
OH CH2CH3
2. 1,3 - difluorobenzene
Step 1: Draw the benzene ring
The parent structure is a benzene ring (\( \text{C}_6\text{H}_6 \) with a cyclic, conjugated double - bond system).
Step 2: Attach the fluorine substituents
We attach fluorine atoms (\( -\text{F} \)) at the 1st and 3rd carbon atoms of the benzene ring. The line - bond structure is:
F
|
C - C - C - F
| | |
C C C
| | |
C - C - C
(where the carbons are part of the benzene ring, and the double bonds are distributed in the conjugated system. The condensed formula can be represented as \( \text{C}_6\text{H}_4\text{F}_2 \) with the two F atoms at positions 1 and 3 relative to each other on the benzene ring.)
3. Propyl butanoate
Step 1: Identify the functional group and the two parts of the ester
Propyl butanoate is an ester. Esters have the general formula \( \text{RCOOR}' \), where \( \text{RCOO}^- \) comes from the carboxylic acid (butanoic acid) and \( \text{R}' \) comes from the alcohol (propanol).
Step 2: Derive the structure from the acid and alcohol parts
- The butanoate part: Butanoic acid has the formula \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COOH} \). When it forms the ester, it becomes \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COO}^- \).
- The propyl part: Propanol has the formula \( \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} \). When it forms the ester, the \( -\text{OCH}_2\text{CH}_2\text{CH}_3 \) part comes from propanol.
- The condensed structure of propyl butanoate is \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COOCH}_2\text{CH}_2\text{CH}_3 \). The line - bond structure:
CH3 - CH2 - CH2 - C(=O) - O - CH2 - CH2 - CH3
Final Answers (Structures)
- 3 - ethylhexan - 2 - ol: Condensed: \( \text{CH}_3-\text{CH}(\text{OH})-\text{CH}(\text{C}_2\text{H}_5)-\text{CH}_2-\text{CH}_2-\text{CH}_3 \); Skeletal: As shown above.
- 1,3 - difluorobenzene: Skeletal: As shown above; Condensed: \( \text{C}_6\text{H}_4\text{F}_2 \) (with F at 1 and 3).
- Propyl butanoate: Condensed: \( \text{CH}_3\text{CH}_2\text{CH}_2\text{COOCH}_2\text{CH}_2\text{CH}_3 \); Skeletal: As shown above.