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Step1: Balance reaction 7: Match atoms
Count N and O on product side: 2 N, 4 O.
For reactants: $2\text{NO} + \text{O}_2$ gives 2 N, $2+2=4$ O, matching product $2\text{NO}_2$.
Step2: Balance reaction 8: Balance Br first
$\text{AlBr}_3$ has 3 Br, so $\text{KBr}$ needs coefficient 3: $\text{AlBr}_3 + \text{K}
ightarrow 3\text{KBr} + \text{Al}$
Step3: Balance reaction 8: Balance K
3 K on product, so K reactant gets 3: $1\text{AlBr}_3 + 3\text{K}
ightarrow 3\text{KBr} + 1\text{Al}$
Step4: Balance reaction 9: Balance F first
$\text{PdF}_2$ has 2 F, $\text{FeF}_2$ has 2 F, so set $\text{FeO}$ and $\text{PdF}_2$ to 1: $\text{FeO} + \text{PdF}_2
ightarrow \text{FeF}_2 + \text{PdO}$
Step5: Verify reaction 9: Check all atoms
1 Fe, 1 O, 1 Pd, 2 F on both sides.
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- $\boldsymbol{2NO + O_2}$
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ightarrow 3\text{KBr} + 1\text{Al}$
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ightarrow 1\text{FeF}_2+1\text{PdO}$