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- combining which of the following substances with germanium will cause the germanium to emit free electrons?
a. gallium
b. aluminum
c. indium
d. bismuth
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To determine which substance causes germanium to emit free electrons, we analyze the doping of semiconductors. Germanium is a semiconductor. Doping with a pentavalent (5 - valence - electron) element creates an n - type semiconductor (with free electrons). Bismuth (Bi) is pentavalent (group 15 element, has 5 valence electrons), while gallium, aluminum, and indium are trivalent (group 13, 3 valence electrons) and form p - type semiconductors (with holes, not free electrons as the majority carrier). So combining germanium with bismuth (a pentavalent dopant) will introduce free electrons.
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D. Bismuth