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question from a molecule point of view, how is liquid water at 100° c similar and different than water vapor at 100° c?
Both liquid water and water vapor at 100°C are made of H₂O molecules. In liquid water, molecules are closer - packed with stronger intermolecular forces and more restricted motion. In water vapor, molecules are far apart, have weaker intermolecular forces and more freedom of motion.
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Similarity: Both consist of H₂O molecules. Difference: In liquid water, molecules are closer - packed with stronger intermolecular forces and less freedom of motion; in water vapor, molecules are far apart with weaker intermolecular forces and more freedom of motion.