QUESTION IMAGE
Question
question 7 (4 points)
balance the following half - reaction in an acidic solution:
hno$_{2(aq)}$ → no$_{3}^{-}$(aq)
Step1: Determine oxidation states
The oxidation state of N in $HNO_2$ is +3 and in $NO_3^-$ is +5. The change in oxidation state is +2, so 2 electrons are lost.
Step2: Balance atoms other than H and O
N atoms are already balanced as there is 1 N on each side.
Step3: Balance O atoms
There are 2 O in $HNO_2$ and 3 O in $NO_3^-$. Add 1 $H_2O$ to the left - hand side to balance O atoms: $HNO_2(aq)+H_2O(l)\to NO_3^-(aq)$.
Step4: Balance H atoms
There are 3 H on the left - hand side. Add 3 $H^+$ to the right - hand side to balance H atoms: $HNO_2(aq)+H_2O(l)\to NO_3^-(aq)+3H^+(aq)$.
Step5: Balance charge
The left - hand side has a net charge of 0, and the right - hand side has a net charge of $3+( - 1)=+2$. Add 2 electrons to the right - hand side to balance the charge: $HNO_2(aq)+H_2O(l)\to NO_3^-(aq)+3H^+(aq)+2e^-$
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$HNO_2(aq)+H_2O(l)\to NO_3^-(aq)+3H^+(aq)+2e^-$