QUESTION IMAGE
Question
complete the following table. identify the type of bonding in each substance. click on the radio button identifying the substance with the highest melting point.
| substance | bonding | highest melting point |
|---|---|---|
| $ccl_{4}$ | select | |
| $alcl_{3}$ | select | |
| $cf_{4}$ | select |
Step1: Analyze $S_8$
$S_8$ is a molecular solid. The sulfur - sulfur bonds within the $S_8$ molecule are covalent, and the intermolecular forces between $S_8$ molecules are London - dispersion forces.
Step2: Analyze $CCl_4$
$CCl_4$ is a molecular compound. The carbon - chlorine bonds are covalent, and the intermolecular forces are London - dispersion forces due to its non - polar nature.
Step3: Analyze $AlCl_3$
$AlCl_3$ is a covalent compound in the gas phase and exists as a dimer $Al_2Cl_6$. In the solid, it has some ionic character due to the polarization of the chloride ions by the aluminum ion, but it is mainly covalent with relatively weak intermolecular forces.
Step4: Analyze $CF_4$
$CF_4$ is a molecular compound. The carbon - fluorine bonds are covalent, and the intermolecular forces are London - dispersion forces as it is non - polar.
Step5: Compare melting points
Among these molecular substances, the melting point is related to the strength of the intermolecular forces. The strength of London - dispersion forces increases with the molar mass. The molar mass of $S_8$ ($M = 8\times32\ g/mol=256\ g/mol$), $CCl_4$ ($M=(12 + 4\times35.5)\ g/mol = 154\ g/mol$), $AlCl_3$ ($M=(27+3\times35.5)\ g/mol=133.5\ g/mol$), $CF_4$ ($M=(12 + 4\times19)\ g/mol = 88\ g/mol$). Since $S_8$ has the highest molar mass among them, it has the strongest London - dispersion forces and thus the highest melting point.
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| Substance | Bonding | Highest Melting Point |
|---|---|---|
| $CCl_4$ | Covalent (intramolecular), London - dispersion (intermolecular) | |
| $AlCl_3$ | Covalent (predominantly, with some ionic character), weak intermolecular forces | |
| $CF_4$ | Covalent (intramolecular), London - dispersion (intermolecular) |