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Step1: Balance the reaction
First, balance the chemical equation:
Step2: Find moles of Na
Calculate moles of Na from mass:
$$n_{\text{Na}} = \frac{45\ \text{g}}{22.99\ \text{g/mol}} = 1.957\ \text{mol}$$
Step3: Moles of NaCl from Na
Use mole ratio (2:2) to find NaCl moles:
$$n_{\text{NaCl (from Na)}} = 1.957\ \text{mol} \times \frac{2}{2} = 1.957\ \text{mol}$$
Step4: Mass of NaCl from Na
Convert moles to grams (molar mass of NaCl = $22.99 + 35.45 = 58.44\ \text{g/mol}$):
$$m_{\text{NaCl (from Na)}} = 1.957\ \text{mol} \times 58.44\ \text{g/mol} = 114.4\ \text{g}$$
Step5: Find moles of Cl₂
Calculate moles of Cl₂ from mass:
$$n_{\text{Cl}_2} = \frac{35\ \text{g}}{70.90\ \text{g/mol}} = 0.4937\ \text{mol}$$
Step6: Moles of NaCl from Cl₂
Use mole ratio (1:2) to find NaCl moles:
$$n_{\text{NaCl (from Cl}_2\text{)}} = 0.4937\ \text{mol} \times \frac{2}{1} = 0.9874\ \text{mol}$$
Step7: Mass of NaCl from Cl₂
Convert moles to grams:
$$m_{\text{NaCl (from Cl}_2\text{)}} = 0.9874\ \text{mol} \times 58.44\ \text{g/mol} = 57.7\ \text{g}$$
Step8: Identify limiting reactant
The reactant that produces less product ($\text{Cl}_2$) is limiting. The theoretical yield is the smaller mass of NaCl.
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Balanced reaction: $2\text{Na} + \text{Cl}_2
ightarrow 2\text{NaCl}$
Theoretical yield of NaCl: $57.7\ \text{g}$
Limiting reactant: $\text{Cl}_2$