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QUESTION IMAGE

1. if the $\\delta g^{\\circ\\prime}$ of the reaction $s \ ightarrow p$…

Question

  1. if the $\delta g^{\circ\prime}$ of the reaction $s \

ightarrow p$ is $-50\\ \mathrm{kj\\ mol^{-1}}$ ($-12\\ \mathrm{kcal\\ mol^{-1}}$), the reaction will: \\(\boldsymbol{\vee_1}\\)
(a) never reach equilibrium.
(b) proceed spontaneously from left to right.
(c) proceed rapidly because of the large negative $\delta g^{\circ\prime}$.
(d) never reach equilibrium because of the large negative $\delta g^{\circ\prime}$.

Explanation:

Brief Explanations

A negative standard Gibbs free energy change ($\Delta G^\circ$) indicates a reaction is thermodynamically spontaneous in the forward direction (from reactant S to product P). $\Delta G^\circ$ does not determine reaction rate (so "rapidly" is incorrect), and even with a large negative value, reactions will still reach equilibrium where both S and P are present (just with a very high concentration of P).

Answer:

(b) proceed spontaneously from left to right.