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use the observation in the first column to answer the question in the s…

Question

use the observation in the first column to answer the question in the second column.

observationquestion
the enthalpy of vaporization of substance c is smaller than that of substance d.which has the higher boiling point?<br>substance c<br>substance d<br>neither, c and d have the same boiling point.<br>its impossible to know without more information.
at 71 $^{circ}c$, substance e has a vapor pressure of 123. torr and substance f has a vapor pressure of 103. torr.which has a higher enthalpy of vaporization?<br>substance e<br>substance f<br>neither, e and f have the same enthalpy of vaporization.<br>its impossible to know without more information.

Explanation:

Step1: Recall boiling - point and vapor - pressure relationship

Substances with lower boiling points have higher vapor pressures at a given temperature. Since Substance A boils at 39 °C and Substance B boils at 64 °C, Substance A has a higher vapor pressure.

Step2: Recall enthalpy of vaporization and boiling - point relationship

A higher enthalpy of vaporization generally means a higher boiling point. Since the enthalpy of vaporization of Substance C is smaller than that of Substance D, Substance D has a higher boiling point.

Step3: Recall vapor - pressure and enthalpy of vaporization relationship

Substances with lower vapor pressures at a given temperature have higher enthalpies of vaporization. Since Substance F has a lower vapor pressure (103 torr) than Substance E (123 torr) at 71 °C, Substance F has a higher enthalpy of vaporization.

Answer:

  1. Substance A
  2. Substance D
  3. Substance F