QUESTION IMAGE
Question
which equations represent precipitation reactions?
□ na₂s + febr₂ → 2nabr + fes
□ mgso₄ + cacl₂ → mgcl₂ + caso₄
□ lioh + nh₄i → lii + nh₄oh
□ 2nacl + k₂s → na₂s + 2kcl
□ agno₃ + nacl → agcl + nano₃
To determine which equations represent precipitation reactions, we need to recall that a precipitation reaction is a type of double - displacement reaction where an insoluble solid (precipitate) is formed from the reaction of two aqueous solutions. We can use the solubility rules to identify if a precipitate is formed.
Step 1: Analyze \(Na_{2}S + FeBr_{2}\to2NaBr + FeS\)
- Sodium sulfide (\(Na_{2}S\)) and iron(II) bromide (\(FeBr_{2}\)) are both soluble in water (since most sodium salts and most bromide salts are soluble).
- The product iron(II) sulfide (\(FeS\)) is insoluble in water (sulfides of transition metals are generally insoluble). So, a precipitate (\(FeS\)) is formed. This is a precipitation reaction.
Step 2: Analyze \(MgSO_{4}+CaCl_{2}\to MgCl_{2}+CaSO_{4}\)
- Magnesium sulfate (\(MgSO_{4}\)) and calcium chloride (\(CaCl_{2}\)) are soluble in water (most sulfate salts and most chloride salts are soluble).
- The product calcium sulfate (\(CaSO_{4}\)) has limited solubility in water (it is considered slightly soluble or insoluble in many cases, and will precipitate out). So, this is a precipitation reaction.
Step 3: Analyze \(LiOH + NH_{4}I\to LiI+NH_{4}OH\)
- Lithium hydroxide (\(LiOH\)) and ammonium iodide (\(NH_{4}I\)) are soluble.
- The product ammonium hydroxide (\(NH_{4}OH\)) is unstable and decomposes into \(NH_{3}\) and \(H_{2}O\), and lithium iodide (\(LiI\)) is soluble. There is no precipitate formed. This is not a precipitation reaction.
Step 4: Analyze \(2NaCl + K_{2}S\to Na_{2}S + 2KCl\)
- Sodium chloride (\(NaCl\)) and potassium sulfide (\(K_{2}S\)) are soluble.
- The products sodium sulfide (\(Na_{2}S\)) and potassium chloride (\(KCl\)) are also soluble (sodium salts and potassium salts are generally soluble). There is no precipitate formed. This is not a precipitation reaction.
Step 5: Analyze \(AgNO_{3}+NaCl\to AgCl + NaNO_{3}\)
- Silver nitrate (\(AgNO_{3}\)) and sodium chloride (\(NaCl\)) are soluble.
- The product silver chloride (\(AgCl\)) is insoluble in water (chlorides of silver, lead, and mercury(I) are insoluble). So, a precipitate (\(AgCl\)) is formed. This is a precipitation reaction.
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The equations that represent precipitation reactions are:
- \(Na_{2}S + FeBr_{2}\to2NaBr + FeS\)
- \(MgSO_{4}+CaCl_{2}\to MgCl_{2}+CaSO_{4}\)
- \(AgNO_{3}+NaCl\to AgCl + NaNO_{3}\)